کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1324821 | 977356 | 2008 | 5 صفحه PDF | دانلود رایگان |
A highly efficient air-initiated hydrosilylation of unactivated alkynes and alkenes and dehalogenation of halohydrocarbons with tris(trimethylsilyl)silane ((TMS)3SiH) as a reducing agent has been established under solvent-free conditions. These observations demonstrate that the potential and versatility of air to function as a competent initiator for Si–H bond activations. It can rival organic initiators and metal catalysts in its efficiency and is a superior initiating system from economic, environmentally sound and practical perspectives.
An efficient air-initiated highly regio- and stereoselective hydrosilylation of unactivated alkynes and alkenes and dehalogenation reaction of organic halides with tris(trimethylsilyl)silane as a reducing agent has been developed under solvent-free conditions.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 12, 1 June 2008, Pages 2188–2192