کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1324902 | 977358 | 2011 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: NMR approach for the identification of dinuclear and mononuclear complexes: The first detection of [Pd(SPh)2(PPh3)2] and [Pd2(SPh)4(PPh3)2] – The intermediate complexes in the catalytic carbon–sulfur bond formation reaction NMR approach for the identification of dinuclear and mononuclear complexes: The first detection of [Pd(SPh)2(PPh3)2] and [Pd2(SPh)4(PPh3)2] – The intermediate complexes in the catalytic carbon–sulfur bond formation reaction](/preview/png/1324902.png)
In the present study we have analyzed the nature of palladium complexes in the catalytic system for selective carbon–sulfur bond formation via the addition of S–S and S–H bonds to alkynes. For the first time the mononuclear and dinuclear palladium complexes were clearly detected by DOSY NMR under the catalytic conditions. It was demonstrated that the concentration of these palladium complexes strongly depends on the amount of phosphine ligand available under reaction conditions.
Detection of mononuclear and dinuclear palladium complexes was carried out by DOSY NMR under catalytic conditions. The concentration of these palladium complexes was found strongly dependent on the amount of phosphine ligand available in the system. It was evidenced that both types of complexes can contribute to the product formation.Figure optionsDownload as PowerPoint slideResearch highlights
► Mononuclear and dinuclear transition metal complexes detection by DOSY NMR.
► The nature of the catalytic system by in situ NMR monitoring.
► Catalytic activity of mononuclear and dinuclear transition metal complexes.
Journal: Journal of Organometallic Chemistry - Volume 696, Issue 1, 1 January 2011, Pages 400–405