کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325192 | 977373 | 2007 | 5 صفحه PDF | دانلود رایگان |
Transition metal-catalyzed dehydrocoupling is a relatively new method for main group element–element bond formation, providing a facile alternative to salt metathesis processes. Lewis acid–base adducts of Groups 13 and 15 can undergo dehydrocoupling with both early and late transition metals and complexes thereof to yield rings, chains and macromolecules based on a framework of alternating B–N or B–P atoms. Evidence is also provided for Group 13 hydrides acting as poisons towards heterogeneous dehydrocoupling catalysts.
Lewis acid–base adducts of Groups 13 and 15 can undergo dehydrocoupling with both early and late transition metals and complexes thereof to yield rings, chains and macromolecules based on a framework of alternating B–N or B–P atoms. Evidence is also provided for Group 13 hydrides acting as poisons towards heterogeneous dehydrocoupling catalysts.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 13, 1 June 2007, Pages 2849–2853