کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325243 | 1499945 | 2009 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Arene ruthenium metallacycles containing chelating thioamide ligands Arene ruthenium metallacycles containing chelating thioamide ligands](/preview/png/1325243.png)
Cationic, chiral arene ruthenium complexes of the type [Ru(η6-cym)(PPh3){κ2N,S-PhNC(S)R}]BPh4 were prepared in high yields by refluxing a mixture containing [(η6-cym)RuCl2]2, Ph3P, PhNHC(S)R, NaBPh4 and Et3N in MeOH. A series of seven complexes with different thioamide ligands was prepared and fully characterised by spectroscopic methods including NMR spectroscopy and electrospray mass spectrometry. The solid-state structures of two complexes were determined by single crystal X-ray diffraction.
Cationic, chiral arene ruthenium complexes of the type [Ru(η6-cym)(PPh3){κ2N,S-PhNC(S)R}]BPh4 were prepared in high yields by refluxing a mixture containing [(η6-cym)RuCl2]2, Ph3P, PhNHC(S)R, NaBPh4 and Et3N in MeOH. A series of seven complexes with different thioamide ligands was prepared and fully characterised by spectroscopic methods and X-ray diffraction.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issues 9–10, 15 April 2009, Pages 1283–1288