Mechanistic study of the addition reaction of TeCl4 to alkynes: Participation of TeCl3 centered-radical

The mechanism of the addition reaction of TeCl4 to alkynes was indirectly established by the detection of TeCl3 centered radicals using EPR spin trapping, ESI-MS and ESI-MS/MS characterization.

The mechanism of the addition reaction of TeCl4 to alkynes was indirectly established by the detection of TeCl3 centered radicals using EPR spin trapping, ESI-MS and ESI-MS/MS characterization.Figure optionsDownload as PowerPoint slide