کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325882 | 1499944 | 2010 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Syntheses and molecular structures of some polyfluoroaryldiynyl–ruthenium complexes Syntheses and molecular structures of some polyfluoroaryldiynyl–ruthenium complexes](/preview/png/1325882.png)
Lithiated Ru(CCCCH)(dppe)Cp∗ reacts with polyfluoroaromatic compounds C6F5X (X = F, OMe, CN, NO2) and C10F8 to give novel polyfluoroaryldiynyls end-capped with the Ru(dppe)Cp∗ group. Addition of tcne to Ru(CCCCC6F5)(dppe)Cp∗ afforded the butadienynyl Ru{CCC[C(CN)2]C(C6F5)C(CN)2}(dppe)Cp∗, while protonation with HBF4·OEt2 resulted in cycloaddition to give [1,3-{Cp∗(dppe)RuCC}2{μ-C4H(C6F5)2}]BF4. XRD molecular structures of complexes with X = F, CN, OMe and the C10F7 derivative are reported.
Lithiated Ru(CCCCH)(dppe)Cp∗ reacts with C6F5X (X = F, OMe, CN, NO2) and C10F8 to give novel polyfluoroaryldiynyls end-capped with the Ru(dppe)Cp∗ group. Addition of tcne to Ru(CCCCC6F5)(dppe)Cp∗ afforded the butadienynyl Ru{CCC[C(CN)2]C(C6F5)C(CN)2}(dppe)Cp∗, while protonation with HBF4·OEt2 resulted in cycloaddition to give [1,3-{Cp∗(dppe)RuCC}2{μ-C4H(C6F5)2}]BF4.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 695, Issues 10–11, 15 May 2010, Pages 1561–1568