Synthesis and characterization of new metal-free and metallophthalocyanines containing macrocyclic moieties

The synthesis and characterization of new metal-free 7 and metallophthalocyanines 8, 9 carrying macrocyclic N2S2O4 donor groups on peripheral positions have been investigated. Phthalonitrile derivative 6 was synthesized according to Rosenmund von Braun procedure from compound 5. The novel compounds were characterized by elemental analysis, IR, 1H and 13C NMR, UV–Vis and MS spectra data.

The synthesis and characterization of new metal-free 7 and metallophthalocyanines 8, 9 carrying macrocyclic N2S2O4 donor groups on peripheral positions have been investigated. Phthalonitrile derivative 6 was synthesized according to Rosenmund von Braun procedure from compound 5. The novel compounds were characterized by elemental analysis, IR, 1H and 13C NMR, UV–Vis and MS spectra data.Figure optionsDownload as PowerPoint slide