کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326039 | 977415 | 2008 | 8 صفحه PDF | دانلود رایگان |
The cyclopalladation of 3,5-bis(diphenylphosphinothioyl)pyridine afforded new κ3S,C,S-pincer palladium complexes with a σ-bond between Pd and 4C of the centered 3,5-pyridinediyl unit. By utilizing the quaternization and complexation ability of the pyridine imine nitrogen (Npy) atom, various new pincer-type complexes, including hetero-binuclear complexes, have been synthesized.
The cyclopalladation of 3,5-bis(diphenylphosphinothioyl)pyridine afforded new κ3S,C,S-pincer palladium complexes with a σ-bond between Pd and 4C of the centered 3,5-pyridinediyl unit. By utilizing the quaternization and complexation ability of the pyridine imine nitrogen (Npy) atom, various new pincer-type complexes, including hetero-binuclear complexes, have been synthesized.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 6, 15 March 2008, Pages 1109–1116