کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326157 | 977417 | 2010 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, crystal structure, antioxidation and DNA-binding properties of the Ln complexes with 1-phenyl-3-methyl-5-hydroxypyrazole-4-carbaldhyde-(benzoyl)hydrazone
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Two lanthanide complexes (Ln = La, Pr) with a PMFP Schiff-base, 1-phenyl-3-methyl-5-hydroxypyrazole-4-carbaldhyde-(benzoyl)hydrazone (H2L) were synthesized and characterized. The crystal structure of the La complex was determined by single-crystal X-ray diffraction, the coordination polyhedron is a tricapped trigonal prism configuration. Furthermore, the DNA-binding properties and abilities of antioxidation for hydroxyl radicals of the ligand and its Ln complex were investigated. The results showed that lanthanide complexes with PMFP Schiff-base have many potential practical applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 695, Issue 3, 1 February 2010, Pages 415-422
Journal: Journal of Organometallic Chemistry - Volume 695, Issue 3, 1 February 2010, Pages 415-422
نویسندگان
Hong-Ge Li, Zheng-Yin Yang, Bao-Dui Wang, Jin-Cai Wu,