کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1326258 1499954 2005 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Syntheses and molecular structures of group 8 benzonitrile complexes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Syntheses and molecular structures of group 8 benzonitrile complexes
چکیده انگلیسی

The molecular structures of eight nitrile complexes of general form [M(NCC6H4R-4)(L2)Cp′]PF6 [M = Fe, Ru; L2 = dppe, (PPh3)2; Cp′ = Cp, Cp*] are reported and discussed in terms of the nature of the M–N interaction. Data are consistent with a predominantly σ-interaction, similar to that found in related acetylide complexes, with little evidence for metal to nitrile π-back bonding interactions.

The molecular structures of eight nitrile complexes of general form [M(NCC6H4R-4)(L2)Cp′]PF6 [M = Fe, Ru; L2 = dppe, (PPh3)2; Cp′ = Cp, Cp*] are reported and discussed in terms of the nature of the M–N interaction. Data are consistent with a predominantly σ-interaction, similar to that found in related acetylide complexes, with little evidence for metal to nitrile π-back bonding interactions.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issues 21–22, 1 November 2005, Pages 4908–4919
نویسندگان
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