کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326258 | 1499954 | 2005 | 12 صفحه PDF | دانلود رایگان |

The molecular structures of eight nitrile complexes of general form [M(NCC6H4R-4)(L2)Cp′]PF6 [M = Fe, Ru; L2 = dppe, (PPh3)2; Cp′ = Cp, Cp*] are reported and discussed in terms of the nature of the M–N interaction. Data are consistent with a predominantly σ-interaction, similar to that found in related acetylide complexes, with little evidence for metal to nitrile π-back bonding interactions.
The molecular structures of eight nitrile complexes of general form [M(NCC6H4R-4)(L2)Cp′]PF6 [M = Fe, Ru; L2 = dppe, (PPh3)2; Cp′ = Cp, Cp*] are reported and discussed in terms of the nature of the M–N interaction. Data are consistent with a predominantly σ-interaction, similar to that found in related acetylide complexes, with little evidence for metal to nitrile π-back bonding interactions.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 690, Issues 21–22, 1 November 2005, Pages 4908–4919