کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1326333 | 977425 | 2007 | 7 صفحه PDF | دانلود رایگان |
The synthesis of novel N-acetyl-N,N-dipyrid-2-yl complexes of RhI and IrI, i.e. [RhCl(CH3CONPy2)(COD)] (1) and [IrCl(CH3CONPy2)(COD)] (2), respectively, is described. Upon prolonged treatment in CH2Cl2 at room temperature, complex 1 is transformed into a cationic Rh-complex, i.e. [Rh(CH3CONPy2)(COD)+RhCl2(COD)−] (1a). Compound 1a crystallizes in the monoclinic space group P21/c, complex 2 crystallizes in the triclinic space group P1¯. Compound 1 was investigated for its catalytic activity in the hydroformylation of cyclooctene as well as of 1-octene. In addition, 1 was used in various carbonyl hydrosilylation reactions of both aldehydes and ketones. There, turn-over numbers up to 50 000 and yields in the range of 85–100% were observed. Finally, compound 1 was successfully used for the polymerization of N2CHCOOEt yielding highly stereoregular poly(ethoxycarbonylcarbene) with Mw = 67 000 g/mol and a polydispersity index (PDI) of 2.59.
Novel N-Acetyl-N,N-dipyrid-2-yl complexes of RhI and IrI, i.e. [RhCl(CH3CONPy2)(COD)] (1) and [IrCl(CH3CONPy2)(COD)] (2) have been prepared and used in hydroformylation, carbonyl hydrosilylation reactions. compound 1 was successfully used for the polymerization of N2CHCOOEt.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 23, 1 November 2007, Pages 5272–5278