Tuning the hemilabile behaviour of a thioether-pyrazole ligand on Pd(II) complexes with diphosphines

► Heteroleptic Pd(II) complexes containing pyrazole-thioether (NS) and diphosphine (PˆP) were synthesised. ► We are interested in the study of the coordination of NS-hybrid ligands and their potential hemilability. ► 1H NMR and 31P{1H} NMR date were applied to characterize the produced linkage isomers.