کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1326640 | 977439 | 2011 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and properties of 5-ferrocenyl-1H-pyrazole-3-carbaldehydes Synthesis and properties of 5-ferrocenyl-1H-pyrazole-3-carbaldehydes](/preview/png/1326640.png)
New ferrocene derivatives – ethyl esters of 1-aryl-5-ferrocenyl-1H-pyrazole-3-carboxylic acids were synthesized. The corresponding aldehydes were obtained from acid esters in two steps. The reductive amination reaction of 5-ferrocenyl-1-phenyl-1H-pyrazole-3-carbaldehyde was studied. Several of these compounds were investigated by cyclic voltammetry. All of them exhibited a reversible one-electron oxidation–reduction wave owing to the ferrocene–ferricinium redox couple with a positive shift (0.51–0.69 V) compared with that of ferrocene (0.46 V). The X-ray crystal structure of the ethyl ether 1-(3-chloro-2-fluorophenyl)-5-ferrocenyl-1H-pyrazole-3-carboxylic acid is also presented.
New ferrocene derivatives 5-ferrocenyl-1-aryl-3-pyrazolecarbaldehydes were synthesized. The reductive amination reaction of 5-ferrocenyl-1-phenyl-1H-pyrazole-3-carbaldehyde was studied. Compounds were investigated by cyclic voltammetry. All exhibited a reversible one-electron oxidation–reduction wave owing to the ferrocene–ferrocenium redox couple. The X-ray crystal structure of the ethyl 1-(3-chloro-2-fluorophenyl)-5-ferrocenyl-1H-pyrazole-3-carboxylate is also presented.Figure optionsDownload as PowerPoint slideHighlights
► New 5-ferrocenyl-1-aryl-3-pyrazolecarbaldehydes were synthesized.
► The reductive amination reaction of 5-ferrocenyl-1-phenyl-1H-pyrazole-3-carbaldehyde was studied.
► The X-ray crystal structure of the ethyl 1-(3-chloro-2-fluorophenyl)-5-ferrocenyl-1H-pyrazole-3-carboxylate is also presented.
Journal: Journal of Organometallic Chemistry - Volume 696, Issue 10, 15 May 2011, Pages 2108–2115