کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1326872 | 977448 | 2008 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Preparation, characterization, and catalytic properties of ruthenium nitrosyl complexes with polypyrazolylmethane ligands Preparation, characterization, and catalytic properties of ruthenium nitrosyl complexes with polypyrazolylmethane ligands](/preview/png/1326872.png)
Ruthenium(II) nitrosyl complexes with polypyrazolylmethanes, [(Bpm)Ru(NO)Cl3] [Bpm = bis(1-pyrazolyl)methane, 1], [(Bpm∗)Ru(NO)Cl3] [Bpm∗ = bis(3,5-dimethyl-1-pyrazolyl)methane, 2], [(Tpm)Ru(NO)Cl2][PF6] [Tpm = tris(1-pyrazolyl)methane, 3], and [(Tpm∗)Ru(NO)Cl2][PF6] [Tpm∗ = tris(3,5-dimethyl-1-pyrazolyl)methane, 4], have been synthesized and characterized. The solid-state structures of [(Bpm∗)Ru(NO)Cl3] (2) and [(Tpm∗)Ru(NO)Cl2][PF6] (4) were determined by single-crystal X-ray crystallographic analyses. These complexes have been tested as catalysts in the transfer hydrogenation of several ketones under mild conditions.
Four ruthenium(II) nitrosyl complexes with the polypyrazolylmethane ligands, [(Bpm)Ru(NO)Cl3] (1), [(Bpm∗)Ru(NO)Cl3] (2), [(Tpm)Ru(NO)Cl2][PF6] (3), and [(Tpm∗)Ru(NO)Cl2][PF6] (4), were prepared and characterized. The structures of complexes 2 and 4 have been determined by X-ray crystallographic analysis. These complexes have been tested as catalysts in the transfer hydrogenation of ketones.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 26, 15 December 2008, Pages 3851–3857