کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1326946 977453 2014 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Molybdenum hexacarbonyl supported on functionalized multi-wall carbon nanotubes: Efficient and highly reusable catalysts for epoxidation of alkenes with tert-butyl hydroperoxide
ترجمه فارسی عنوان
هگزاکربنایل مولیبدن بر روی نانولوله های کربنی چند دیواره کاربرد دارد: کاتالیزورهای کارآمد و قابل استفاده مجدد برای اپوکسید شدن الکل های با هیدروپراکسید تربت بوتیل
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی

In the present work, highly efficient epoxidation of alkenes catalyzed by Mo(CO)6 supported on amines modified multi-wall carbon nanotubes, MWCNTs, is reported. The prepared catalysts were characterized by elemental analysis, scanning electron microscopy, FT-IR and diffuse reflectance UV–Vis spectroscopic methods. These new heterogenized catalysts, [Mo(CO)6@amines-MWCNT], were used as highly efficient catalysts for epoxidation of alkenes with tert-BuOOH. These robust catalysts could be reused several times without loss of their catalytic activities.

Highly efficient epoxidation of alkenes catalyzed by Mo(CO)6 supported on amines modified multi-wall carbon nanotubes, MWCNTs, is reported. These new heterogenized catalysts, [Mo(CO)6@amines-MWCNT], were used as highly efficient catalysts for epoxidation of alkenes with tert-BuOOH. These robust catalysts could be reused several times without loss of their catalytic activities.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 695, Issue 17, 1 August 2010, Pages 2014–2021
نویسندگان
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