کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327020 | 977459 | 2010 | 4 صفحه PDF | دانلود رایگان |
The oxidative addition of selenol, HhfSeH (2, Hhf = 9,10,11,12,14,15-hexahydro-9,10[3′,4′]-furanoanthracenyl) with [Pt(η2-nb)(Ph3P)2] (nb = norbornene) in toluene afforded the corresponding hydrido(selenolato) Pt(II) complex [cis-PtH(SeHhf)(Ph3P)2] (3) as a stable compound. Refluxing a xylene solution of 3 produced two isomers of five-membered selenaplatinacycles 4 in moderate yield as an inseparable mixture. In addition, the molecular structures of HhfSeH 2 and the minor selenaplatinacycle 4a were determined by X-ray crystallography.
The oxidative addition of selenol 2 having a 9,10,11,12,14,15-hexahydro-9,10[3′,4′]-furanoanthracenyl group with [Pt(η2-nb)(Ph3P)2] (nb = norbornene) in toluene formed the corresponding hydrido(selenolato) Pt(II) complexes [cis-PtH(SeHhf)(Ph3P)2] (3) as a stable compound. Refluxing a xylene solution of 3 for 3 days produced two isomers of five-membered selenaplatinacycles 4a and 4b in moderate yield as an inseparable mixture.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 695, Issue 7, 1 April 2010, Pages 970–973