کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327256 | 977470 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Side chain-directed complementary cis-coordination of two pyridines on Pd(II): Selective multicomponent assembly of square-, rectangular-, and trigonal prism-shaped molecules
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This paper describes a new strategy to regulate multicomponent assembly from two kinds of pyridine-based ligands and cis-protected Pd(II) ions. The introduction of sterically hindered substituents to only one of the two ligands directs the complementary cis-coordination of the two lingads on the Pd(II) center, leading to the selective multicomponent assembly of two- and three-dimensional polynuclear Pd(II) complexes (e.g., square-, rectangular-, and trigonal prism-shaped molecules).
Complementary cis-coordination of two types of pyridine-based ligands on Pd(II) ions by steric control leads to the selective assembly of two- and three-dimensional polynuclear Pd(II) complexes from multicomponents.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 23, 15 November 2005, Pages 5383–5388
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 23, 15 November 2005, Pages 5383–5388
نویسندگان
Michito Yoshizawa, Muneki Nagao, Kazuhisa Kumazawa, Makoto Fujita,