کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1327300 977473 2005 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Searching for molecular arene hydrogenation catalysis in ionic liquids
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Searching for molecular arene hydrogenation catalysis in ionic liquids
چکیده انگلیسی

Arene hydrogenation by homogeneous catalysts is a highly controversial area of research, with many of the mononuclear complexes shown to catalyse the reaction, being found to be pre-catalysts to nanoparticles, on closer examination. The solvent properties of ionic liquids, i.e., low nucleophilicity and high polarity, make them ideal, at least in principal, for homogeneous arene hydrogenation catalysts. In this paper, we described our attempts to prepare and study such systems, using either simple metal halides or ruthenium complexes including trinuclear ruthenium clusters as catalyst precursors.

Ionic liquids are excellent solvents for conducting hydrogenation reactions and also facilitate catalysis by intact molecular clusters. Our attempts to prove arene hydrogenation by homogeneous catalyst, including molecular clusters, are described.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 15, 1 August 2005, Pages 3552–3557
نویسندگان
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