کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327398 | 977480 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Isolated-palladium complexes for catalyzed telomerization of butadiene with methanol in the presence of water
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Isolated-palladium complexes for catalyzed telomerization of butadiene with methanol in the presence of water Isolated-palladium complexes for catalyzed telomerization of butadiene with methanol in the presence of water](/preview/png/1327398.png)
چکیده انگلیسی
In order to study the performance of organometallic complexes in the telomerization of butadiene with methanol in aqueous medium, we synthesized and characterised hydrosoluble palladium complexes. [(π-allyl)Pd(TPPTS)2]+Cl− complex exhibited strong stability as no degradation was observed after storage at room temperature under air atmosphere for weeks. TON’s up to 36 000 were achieved at 50 °C.
Cationic hydrosoluble palladium complexes were prepared. They were stable at room temperature under air atmosphere for weeks. They were efficient in the telomerization of butadiene with methanol in the presence of water under mild conditions.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 16, 15 July 2009, Pages 2513–2518
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 16, 15 July 2009, Pages 2513–2518
نویسندگان
Julien Mesnager, Emile Kuntz, Catherine Pinel,