کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1327426 977481 2006 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrocatalytic reductive dimerization of the 2,2′-bipyridyl tungsten alkylidyne complex [W(CC6H4NMe2-4)(NCMe)(CO)2{κ2-2,2′-(NC5H4)2}]+
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Electrocatalytic reductive dimerization of the 2,2′-bipyridyl tungsten alkylidyne complex [W(CC6H4NMe2-4)(NCMe)(CO)2{κ2-2,2′-(NC5H4)2}]+
چکیده انگلیسی
Reductive electrodimerization of the cationic tungsten alkylidyne complex [W(CC6H4NMe2-4)(NCMe)(CO)2{κ2-2,2′-(NC5H4)2}]+ has been observed by cyclic voltammetry measurements and verified by subsequent data analysis. The coupled product is deposited on the electrode and appears to act as an electrocatalyst in subsequent potential cycles. Experimental results are supported by DFT computational analysis, which indicates a 2,2′-bipyridyl-centered LUMO and surprisingly little contribution from the MeCN ligand to the frontier HOMOs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 22, 1 November 2006, Pages 4660-4666
نویسندگان
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