کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327501 | 977485 | 2009 | 6 صفحه PDF | دانلود رایگان |

A series of mono- and dinuclear gold(I) phosphine complexes of the type [Au{SeC(OMe)NPh}(P)] [P = PPh3, PTA, P(o-tolyl)3, P(p-MeOC6H4)3] and [Au2{SeC(OMe)NPh}2(μ-PP)] (PP = dppm, dppe, dppp, dppf, dppee) were prepared from the reaction of the appropriate chlorogold(I) phosphine complexes with N-phenyl-O-methylselenocarbamide in the presence of base. These new complexes were fully characterised by spectroscopic techniques and, in several cases, by X-ray crystallography. The differences in the solid-state structures of these selenium complexes were compared with those of some sulfur analogues.
A series of mono- and dinuclear gold(I) phosphine complexes of the type [Au{SeC(OMe)NPh}(P)] [P = PPh3, PTA, P(o-tolyl)3, P(p-MeOC6H4)3] and [Au2{SeC(OMe)NPh}2(μ-PP)] (PP = dppm, dppe, dppp, dppf, dppee) were prepared from the reaction of the appropriate chlorogold(I) phosphine complexes with N-phenyl-O-methylselenocarbamide in the presence of base. These new complexes were fully characterised by spectroscopic techniques and, in several cases, by X-ray crystallography.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 15, 1 July 2009, Pages 2380–2385