کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327503 | 977485 | 2009 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Bridge cleavage reactions of cyclopalladated nitrosamines with thioamides and related compounds
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Bridge cleavage reactions of cyclopalladated nitrosamines with thioamides and related compounds Bridge cleavage reactions of cyclopalladated nitrosamines with thioamides and related compounds](/preview/png/1327503.png)
چکیده انگلیسی
The palladacycle [Pd(μ-O2CMe){κ2C,N-4-MeC6H3N(Me)NO}]2 undergoes bridge cleavage reactions with a variety of compounds containing donor functionalities including thioamides, 8-hydroxyquinoline, thioureas, selenoureas, acetylacetone derivatives, dithiocarbamates, xanthates, as well as bidentate N-donors to afford either monomeric, neutral Pd(II) complexes or monocationic complexes in high yields. A series of 15 different complexes was prepared and fully characterised spectroscopically and, in some cases, by X-ray diffraction. It was also found that in solution the dithiocarbamato complex undergoes a disproportionation reaction to give a bis(cyclometallated) complex.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 15, 1 July 2009, Pages 2395-2401
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 15, 1 July 2009, Pages 2395-2401
نویسندگان
Felix Fuge, Christian W. Lehmann, Jörg Rust, Fabian Mohr,