کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1327642 977496 2006 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Syntheses, structures and electrochemistry of some 1-(η2-allylamino)-1-ferrocenylcarbene complexes of chromium(0), molybdenum(0) and tungsten(0)
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Syntheses, structures and electrochemistry of some 1-(η2-allylamino)-1-ferrocenylcarbene complexes of chromium(0), molybdenum(0) and tungsten(0)
چکیده انگلیسی
The bimetallic chelated complexes (OC)4MC(η2-NHCH2CHCHX)Fc 4/5 [M = Cr: a; Mo: b; W: c; Fc = CpFe(C5H4)] were obtained by photo-decarbonylation/alkene ligation of the unchelated precursor carbene complexes (OC)5MC(NHCH2CHCHX)Fc (2; X = H)/(3; X = CH2OH). The latter exist as mixtures of E- and predominantly Z-isomers. The molecular structures of 4b and 4c were determined by X-ray single-crystal diffraction analyses. The intermetallic communicative effects and the interplay of Fc and η2-alkene moieties of 4a and 4b were assessed by cyclovoltammetry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 5, 15 February 2006, Pages 859-868
نویسندگان
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