کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327820 | 977507 | 2005 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Preparation, X-ray structure, copolymerization with styrene of [(μ-H)Os3(μ-OCNMe2)(CO)9{P(CH2CHCH2)Ph2}] and catalytic properties of the cluster/styrene copolymer Preparation, X-ray structure, copolymerization with styrene of [(μ-H)Os3(μ-OCNMe2)(CO)9{P(CH2CHCH2)Ph2}] and catalytic properties of the cluster/styrene copolymer](/preview/png/1327820.png)
The complex [(μ-H)Os3(μ-OCNMe2)(CO)9{P(CH2CHCH2)Ph2}] derived from the replacement of a lightly-stabilizing NMe3 ligand in [(μ-H)Os3(μ-OCNMe2)(CO)9(NMe3)] by allyldiphenylphosphine molecule was physico-chemically and X-ray structurally characterized and served further as a metal cluster monomer to be immobilized on a polymer surface. The copolymerization of this cluster monomer with styrene was studied. It was found that the cluster molecule, when copolymerized, maintains its integrity and the overall structure. The cluster copolymers obtained have been tested as catalysts for oxidative dehydrogenation and cyclohexenol hydroxylation reactions.
The complex [(μ-H)Os3(μ-OCNMe2)(CO)9{P(CH2CHCH2)Ph2}] derived from the replacement of a lightly-stabilizing NMe3 ligand in [(μ-H)Os3(μ-OCNMe2)(CO)9(NMe3)] by allyldiphenylphosphine molecule was physico-chemically and X-ray structurally characterized and served further as a metal cluster monomer to be immobilized on a polymer surface.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 19, 1 October 2005, Pages 4258–4264