کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1328210 | 977549 | 2007 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Chiral, bridged bis(imidazolin-2-ylidene) complexes of palladium Chiral, bridged bis(imidazolin-2-ylidene) complexes of palladium](/preview/png/1328210.png)
Varieties of chiral, bridged bisimidazolium salts as well as the synthesis of palladium complexes of general formula [bridge{NC(H)C(H)N(R∗)C¯}2PdBr2] with the corresponding chelating N-heterocyclic carbene ligands is reported. This is the first systematic study of chiral bis(imidazolin-2-ylidene)palladium(II) complexes bearing chiral groups on the endocyclic nitrogens. Structural proof of such a chiral palladium(II) complex is presented by way of an X-ray diffraction study of complex 3a.
A systematic study of chiral bis(imidazolin-2-ylidene)palladium(II) complexes is presented, bearing the chiral group on the ring nitrogens. A structural proof of the chiral palladium(II) complexes is represented by a X-ray diffraction study.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 21, 1 October 2007, Pages 4560–4568