کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1328452 | 977574 | 2006 | 5 صفحه PDF | دانلود رایگان |
Treatment of [W(CO)5THF] with diferrocenyl diselenide, Fc2Se2, yielded the novel metal–metal bonded tungsten(I) complex, [W2(μ-SeFc)2(CO)8] (1: Fc = ferrocenyl, [Fe(η5-C5H5)(η5-C5H4)]), which was characterised by NMR and IR spectroscopy, mass spectrometry, and X-ray crystallography. The corresponding tellurium derivative could not be prepared by an analogous route. The X-ray crystal structure of Fc2Te2 has also been determined.
Treatment of [W(CO)5THF] with diferrocenyl diselenide, Fc2Se2, yielded the novel metal–metal bonded tungsten(I) complex, [W2(μ-SeFc)2(CO)8] (1: Fc = ferrocenyl, [Fe(η5-C5H5)(η5-C5H4)]). The corresponding tellurium derivative could not be prepared by an analogous route. The structures of 1 and Fc2Te2 have been determined by X-ray crystallography.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 23, 15 November 2006, Pages 4963–4967