کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1328503 | 977584 | 2006 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and spectral characterization of diorganodiaminosilanes [(ArNH)2SiPhMe] (Ar = 2,6-iPr2C6H3; 2,4,6-Me3C6H2) and lithium silylamide [(2,6-Et2C6H3NLi)(2,6-Et2C6H3NH)SiPh2] Synthesis and spectral characterization of diorganodiaminosilanes [(ArNH)2SiPhMe] (Ar = 2,6-iPr2C6H3; 2,4,6-Me3C6H2) and lithium silylamide [(2,6-Et2C6H3NLi)(2,6-Et2C6H3NH)SiPh2]](/preview/png/1328503.png)
Aminosilanes bearing bulky substituents on nitrogen centers, [(ArNH)2SiPhMe] (Ar = 2,6-iPr2C6H3 (1), 2,4,6-Me3C6H2 (2)) and half-sandwich lithium silylamide [(2,6-Et2C6H3NLi)(2,6-Et2C6H3NH)SiPh2] (3) have been prepared and characterized by elemental analysis, IR, EI mass and NMR (1H and 29Si) spectroscopic studies. The solid state structures of 2 and 3 have been determined by single crystal X-ray diffraction studies. The molecule 2 has a C1 symmetry due to the steric crowding, and the two N–H protons are approximately trans to each other. The amido nitrogen atoms in 2 show significant deviation from trigonal-planar geometry, and as a result, the observed Si–N bonds are marginally longer than those observed in aminosilanes with planar nitrogen atoms. The molecule 3 exists as discrete dimer with an inversion center. The Li ion in 3 forms intramolecular π-complex with the neighboring aryl (2,6-Et2C6H3) group, to form a half-sandwich lithium silylamide.
A rare monolithium salt of a diorganodiaminosilane has been synthesized and structurally characterized; the lithium ion in this compound forms an unusual half-sandwich complex through the interaction of all six carbon atoms an adjacent aryl ring emanating from the –NHAr group on the central silicon.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 15, 15 July 2006, Pages 3260–3266