کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1328576 | 977594 | 2006 | 7 صفحه PDF | دانلود رایگان |

Pt{(S,S)-bdpp}(R)I (bdpp = 2,4-bis(diphenylphosphino)pentane; R = Me, Ph, Bz, 2-Tioph) complexes were formed in alkyl/aryl ligand – iodide ligand-exchange reactions by reacting the corresponding Pt{(S,S)-bdpp}R2 complexes with methyl iodide. The Pt{(S,S)-bdpp}(Me)I complex was isolated and fully characterised. The influence of the X ligand on the platinum-bdpp chelate conformation was investigated in Pt{(S,S)-bdpp}(X)I (X = I, SnCl3, Me) complex series by means of X-ray crystallography.
Pt{(S,S)-bdpp}(X)I (X = I, Me; bdpp = 2,4-bis(diphenylphosphino)pentane) complexes were synthesised in ligand exchange reactions and their structure was determined by X-ray crystallography. Three different platinum-bdpp chelate conformations have been identified.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 12, 1 June 2006, Pages 2846–2852