کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1328662 | 977614 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of chiral chelating N-heterocyclic carbene complexes of ruthenium
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis of chiral chelating N-heterocyclic carbene complexes of ruthenium Synthesis of chiral chelating N-heterocyclic carbene complexes of ruthenium](/preview/png/1328662.png)
چکیده انگلیسی
The first 9-membered chiral chelating bidentate imidazol-2-ylidene ruthenium (II) benzylidene complexes based on a cyclopentane backbone were synthesised and characterised via NMR and HRMS.
The first 9-membered chiral chelating bidentate imidazol-2-ylidene ruthenium (II) benzylidene complexes based on a cyclopentane backbone were synthesised by elaboration of a chiral cyclopentane dibromide to the bisimidazolium salt and then bisimidazolium-2-thione. Reduction of the thione functionality gave access to the bis(imidazol-2-ylidene), which when reacted with Grubbs catalyst affords the air stable chiral chelating bidentate NHC ruthenium benzylidene complexes.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 17, 1 September 2005, Pages 3970–3975
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 17, 1 September 2005, Pages 3970–3975
نویسندگان
Colin Marshall, Mark F. Ward, William T.A. Harrison,