کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1329086 | 978879 | 2011 | 8 صفحه PDF | دانلود رایگان |
The crystal structure of the ternary intermetallic compound Yb3Pd2Sn2 has been determined ab initio from powder X-ray diffraction data. The compound crystallizes as a new structure type in the orthorhombic space group Pbcm and lattice constants a=0.58262(3), b=1.68393(8), c=1.38735(7) nm. Yb3Pd2Sn2 is composed of a complex ∞[Pd2Sn2]δ− polyanionic network in which the Yb ions are embedded. A comparison between this structure and those of Eu3Pd2Sn2 and Ca3Pd2Sn2, other novel polar intermetallic compounds, was made. DC susceptibility and 170Yb Mössbauer spectroscopic measurements indicate a close-to divalent Yb behavior. Moreover, a hybridization between 4f and conduction electrons is suggested by electronic structure calculations and heat capacity measurements.
Graphical AbstractPolyanionic networks for Yb3Pd2Sn2 and Eu3Pd2Sn2.Figure optionsDownload as PowerPoint slideHighlights
► We determined ab initio the crystal structure of the novel ternary Yb3Pd2Sn2 stannide.
► This structure has been compared with those of other polar 3:2:2 stannides discovered in this work.
► Measurements of physical properties on Yb3Pd2Sn2 point to a close-to-divalent Yb ion.
► Electron structure calculation and heat capacity indicate some hybridization between 4f and conduction electrons.
Journal: Journal of Solid State Chemistry - Volume 184, Issue 9, September 2011, Pages 2498–2505