Magnetic and thermodynamic properties of NdT2Ge2 (T=Pd, Ag) compounds

Physical properties of NdPd2Ge2 and NdAg2Ge2, crystallizing with the tetragonal ThCr2Si2-type crystal structure, were investigated by means of magnetic, calorimetric, electrical transport as well as by neutron diffraction measurements. The specific heat studies and neutron diffraction measurements were performed down to 0.30 K and 0.47 K, respectively. Both compounds exhibit antiferromagnetic ordering below TN equal to 1.5 K for NdPd2Ge2 and 1.8 K for NdAg2Ge2. Neutron diffraction data for the latter germanide indicate antiferromagnetic collinear structure described by the propagation vector k=(0.5, 0, 0.5). The Nd magnetic moments equal to 2.24(5) μB at 0.47 K are aligned along the a-axis and have the +− sequence within the crystal unit cell. For NdPd2Ge2 only very small Bragg peaks of magnetic origin were observed in the neutron diffraction patterns measured below TN, thus hampering determination of the magnetic structure. Both compounds exhibit metallic-like electrical conduction. From the specific heat data the crystal electric field (CEF) levels schemes were determined. Difference between the overall CEF splitting in the two compounds is correlated with their structural parameters.

Low-temperature specific heat of NdAg2Ge2 under external magnetic fields. The λ-like anomaly originates from onset of magnetic ordering below 1.80 K. Shifting the anomaly position towards the lower temperatures, when raising the magnetic field, hints at antiferromagnetic behaviors.Figure optionsDownload as PowerPoint slide