Auxiliary aromatic-acid effect on the structures of a series of ZnII coordination polymers: Syntheses, crystal structures, and photoluminescence properties

Five novel ZnII-(pyridyl)imidazole derivative coordination polymers, [Zn(L)2] (1), [Zn2(μ3-OH)L(m-BDC)] (2), [Zn2(μ3-OH)L(p-BDC)]·H2O (3), [Zn2L(BTC)(H2O)]·2.5H2O (4) and [Zn3.5(μ3-OH)L2(BTEC)(H2O)]·H2O (5) (L=4-((2-(pyridine-2-yl)-1H-imidazol-1-yl)methyl)benzoic acid, p-H2BDC=1,4-benzenedicarboxylic acid, m-H2BDC=1,3-benzenedicarboxylic acid, H3BTC=1,3,5-benzenetricarboxylic acid, H4BTEC=1,2,4,5-benzenetetracarboxylic acid), were successfully synthesized under hydrothermal conditions through varying auxiliary aromatic-acid ligands and structurally characterized by X-ray crystallography. Compound 1 exhibits a 1D chain linked via double L bridges. Compound 2 features a well-known pcu topology with bent dicarboxylate ligand (m-H2BDC) as an auxiliary ligand, while 3 displays a bcu network with linear dicarboxylate ligand (p-H2BDC) as an auxiliary ligand. The structure of compound 4 is a novel 3D (3,5)-connected network with (4·62)(4·64·82·10·122) topology. It is interesting that compound 5 shows an intricate (3,4,8)-connected framework with (4·62)(42·63·8)(42·64)(42·618·7·86·10) topology. In addition, their infrared spectra (IR), X-ray powder diffraction (XPRD) and photoluminescent properties were also investigated in detail.

Five novel ZnII-organic architectures have been hydrothermally synthesized through varying auxiliary aromatic-acid ligands and characterized by X-ray diffraction, the photoluminescence properties of compounds 1–5 were studied.Figure optionsDownload as PowerPoint slide