Influence of electrospraying parameters on the microstructure of La0.6Sr0.4Co0.2F0.8O3−δ films for SOFCs

Ceramics can play a remarkable role in the engineering of intermediate temperature solid oxide fuel cells (IT-SOFCs) capable of meeting the ambitious targets of reduced cost and improved lifetime. While mixed ionic–electronic conductors such as LaxSr1−xCoyFe1−yO3−δ are being used as volumic cathodes to increase the catalytic performance of these components, adequate microstructures are also an important requirement for optimal performance, particularly at lower operating temperatures. This work is devoted to the fabrication of La0.6Sr0.4Co0.2Fe0.8O3−δ films on Ce0.9Gd0.1O2−δ substrates by electrostatic spray deposition (ESD) and to the characterization of the microstructural dependence on the deposition conditions. A wide variety of microstructures ranging from dense to porous, with particular features such as reticulation and micro-porosity, were obtained by varying the ESD deposition parameters: nozzle-to-substrate distance (15, 30, 43, 45, and 58 mm), solution flow rate (0.34 and 1.5 mL/h), and substrate temperature (300, 350, 400 and 450 °C). The correlation between deposition parameters and resulting microstructures was systematically studied and put into evidence.

Graphical AbstractThis work is devoted to the fabrication of La0.6Sr0.4Co0.2Fe0.8O3−δ films on dense Ce0.9Gd0.1O2−δ substrates by electrostatic spray deposition (ESD) and to the characterization of the microstructural dependence on the deposition conditions. A wide variety of microstructures ranging from dense to porous, with particular features such as reticulation and micro-porosity, were obtained by varying the nozzle-to-substrate distance, substrate temperature and solution flow rate.Cross-section view of the fractal-like La0.6Sr0.4Co0.2Fe0.8O3−δ cathode film, as-deposited by electrostatic spray deposition.Figure optionsDownload as PowerPoint slide