XPS spectra of the U5+U5+ compounds KUO3KUO3, NaUO3NaUO3 and Ba2U2O7Ba2U2O7

Valence states of uranium in three ternary uranates KUO3KUO3, NaUO3NaUO3 and Ba2U2O7Ba2U2O7 were studied using X-ray photoelectron spectroscopy (XPS). The analysis of the U4f photoelectron peak positions, peak widths at half maximum and satellite positions of U4f peaks, shows that the uranium in these compounds is present in a single valence state, namely U5+U5+. Since the surface of these compounds is extremely susceptible to oxidation, the XPS spectra were measured after a carefully controlled etching of the surface using an Ar+Ar+ ion beam so that the surface oxidation does not affect the XPS studies.

U4f X-ray photoelectron spectroscopy (XPS) spectra of NaUO3NaUO3, KUO3KUO3 and Ba2U2O7Ba2U2O7, indicating single valence state of uranium in these compounds. U4f XPS spectra of UO2UO2(U4+)(U4+) and Cs2U4O13Cs2U4O13(U6+(U6+) are shown for a comparison.Figure optionsDownload as PowerPoint slide