Structure variation and luminescence properties of lanthanide complexes with 1,9-bis [2-(2′-picolylaminoformyl)-1,4,7,9-tetraoxadecane

Using 1,9-salicylamide bissubstituted oxadecane ligand, 1,9-bis [2-(2′-picolylaminoformyl)-1,4,7,9-tetraoxadecane (L), two novel lanthanide complexes have been prepared and well characterized by means of elemental analysis, IR spectroscopy, UV–vis spectroscopy, TGA analysis and single-crystal X-ray diffraction. {[PrL(NO3)3(H2O)2]·CH3OH}n is a 1D zigzag polymer with three-dimensional supramolecular structure formed by hydrogen bonds, while [EuL(NO3)3(H2O)]n is a linear coordination polymer and present an interesting supramolecular double chain, which are very different from the structure of terbium complex reported before. The result reported herein demonstrated that steric crowding associated with the decreasing lanthanide ion radius causes changes of the conformation of the ligand as well as structures. Luminescence studies for the Eu(III) complexes demonstrated that the salicylamide ligand also exhibits a good antennae effect for the Eu(III) ion due to efficient intersystem crossing and ligand-to-metal energy transfer and the Eu(III) ion is well shielded from the surrounding environment.

Structure variation and luminescence properties of lanthanide complexes with 1,9-bis [2-(2′-picolylaminoformyl)-1,4,7,9-tetraoxadecane.Figure optionsDownload as PowerPoint slide