کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1329390 | 1500074 | 2016 | 4 صفحه PDF | دانلود رایگان |
• Structure of Ba2Y0.879UO6+x refined.
• U L-edge XANES demonstrates the U is hexavalent.
• Rare example of a perovskite containing vacancies at the octahedral B-site.
• Y vacancies result in a distortion of the BO6 octahedra.
A combination of S-XRD and NPD demonstrate the structure of Ba2Y0.879UO6+x to be monoclinic in space group I2/m. That the U is hexavalent is evident from the U L2-edge XANES measurements. This appears to be a rare example of a double perovskite containing vacancies at the octahedral B-sites and interstitial oxygen defects, which combine to stabilise hexavalent U and appears to be a consequence of the preparation of the sample in air. The Y vacancies, coupled with anion disorder, results in a distortion of the BO6 octahedra.
The structure of Ba2Y0.879UO6+x is shown to be a rare example of a double perovskite containing vacancies at the octahedral B-sites and interstitial oxygen defects.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 243, November 2016, Pages 8–11