کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1329435 | 1500084 | 2015 | 5 صفحه PDF | دانلود رایگان |
• Two novel Cobalt(II) complexes with tetrazole acetate ligands were synthesized.
• The magnetic properties of two complexes were studied.
• Azide as co-ligand resulted in different structures and magnetic properties.
• The new coordination mode of tetrazole acetate ligand was obtained.
Two new coordination complexes with tetrazole heterocycle ligands bearing acetate groups, [Co(L)2]n (1) and [Co3(L)4(N3)2·2MeOH]n (2) (L=tetrazole-1-acetate) have been synthesized and structurally characterized. Single crystal structure analysis shows that the cobalt-complex 1 has the 3D 3,6-connected (42.6)2(44.62.88.10)-ant topology. By introducing azide in this system, complex 2 forms the 2D network containing the [Co3] units. And the magnetic properties of 1 and 2 have been studied.
The synthesis, crystal structure, and magnetic properties of the new coordination complexes with tetrazole heterocycle ligands bearing acetate groups are reported.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 232, December 2015, Pages 62–66