Crystal-structure and Mössbauer studies of Li1.746Nd4.494FeO9.493

The Li1.746Nd4.494FeO9.493 (LNF) ternary phase, located in the Li2O-rich part of the Li2O–Nd2O3–Fe2O3 system, crystallizes with a cubic unit cell of dimension a=11.9763(3)Å and the space group Im3mIm3m. Refinement on F   resulted in R=1.9%R=1.9%. The structure is comprised of a network of corners, edges and faces sharing the coordination polyhedra of neodymium. In between this skeleton the regular octahedra of oxygen-coordinated iron and trigonal prisms of lithium are located. The Mössbauer spectra revealed the presence of Fe3+, Fe4+ and Fe5+ ions distributed on two symmetry-independent lattice positions.

Representation of the Li1.746Nd4.494FeO9.493 structure.Figure optionsDownload as PowerPoint slide