کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1330007 | 1500117 | 2013 | 5 صفحه PDF | دانلود رایگان |
The barium uranium sulfides Ba3.69US6, BaUS3, and BaU2S5 have been synthesized at 1273, 1323, and 1323 K, respectively. The structures of these compounds have been determined by single-crystal X-ray diffraction methods. They crystallize in space groups D3d6−R3¯c, D2h16−Pnma, and C2h5−P21/c, respectively. Among these three ternaries and Ba2US6 the coordination geometries about the U atoms vary considerably. Ba3.69US6 is a mixed U4+/U5+compound whereas the others are U4+ compounds. The decreasing dimensionality of the four compounds with increasing Ba–to–U content shows the expected trend.
View of the structure of Ba3.69US6 down [1 0 1].Figure optionsDownload as PowerPoint slideHighlights
► The barium uranium sulfides Ba3.69US6,BaUS3, and BaU2S5 have been synthesized and characterized.
► Ba3.69US6 is a new mixed valent U4+/U5+ compound.
► Dimensionality of these compounds decreases with increasing Ba–to–U content.
Journal: Journal of Solid State Chemistry - Volume 199, March 2013, Pages 253–257