کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1330042 | 978938 | 2006 | 6 صفحه PDF | دانلود رایگان |

We prepared samples of cubic γ-MoNx (x ∼0.5) by high-pressure–high-temperature synthesis. N atom site occupancies within the defect rock salt structure were determined from time-of-flight neutron diffraction and powder X-ray diffraction data by Rietveld analysis. The results show that N atoms occupy only octahedral sites within the structure. The semi-metallic compound is a superconductor, with Tc=5.2K determined by SQUID magnetometry. The compressibility of the material was determined by synchrotron X-ray diffraction measurements at high pressure in the diamond anvil cell. The vibrational density of states was studied by Raman scattering spectroscopy.
The neutron observed (+), calculated (−) and difference profiles (bottom trace) for γ-MoN at 290 K.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 179, Issue 6, June 2006, Pages 1762–1767