Mesoporous VN prepared by solid–solid phase separation

We recently reported a simple route to prepare mesoporous, conducting nitrides from Zn containing ternary transition metal oxides. Those materials result from the condensation of atomic scale voids created by the loss of Zn by evaporation, the replacement of 3 oxygen anions by 2 nitrogen anions, and in most cases the loss of oxygen to form water on the reduction of the transition metal. In this report, we present a different route to prepare mesoporous VN from K containing vanadium oxides. In this case, ammonolysis results in a multiphase solid product that contains VN, and other water soluble compounds such as KOH or KNH2. On removing the K containing products by washing with degassed water, only mesoporous VN remains. VN materials with different pore sizes (10 nm–20 nm) were synthesized at 600 °C by varying the reaction time, while larger pores are obtained at higher temperatures (50 nm at 800 °C).

Graphical AbstractThe synthesis process of mesoporous VN from solid–solid separation.Figure optionsDownload as PowerPoint slideHighlights
► Mesoporous VN has been prepared by solid–solid phase separation.
► Mesoporous VN was characterized by Rietveld refinement of PXRD, SEM and nitrogen physisorption.
► VN materials with different pore sizes (10 nm–50 nm) were synthesized.