کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1330433 | 1500109 | 2013 | 11 صفحه PDF | دانلود رایگان |
• We report a novel interesting crystal structure type for mixed sorosilicates containing Y, Yb, and Sc.
• Synthesis of such mixed sorosilicates is possible by a high-temperature flux-growth technique.
• Calculation of Raman vibrations by advanced DFT methods allows a considerably improved interpretation of measured Raman spectra.
Three new, isotypic silicate compounds, BaY4(Si2O7)(Si3O10), SrYb4(Si2O7)(Si3O10) and SrSc4(Si2O7)(Si3O10), were synthesized using high-temperature flux growth techniques, and their crystal structures were solved from single-crystal X-ray intensity data: monoclinic, P21/m, with a=5.532(1)/5.469(1)/5.278(1), b=19.734(4)/19.447(4)/19.221(4), c=6.868(1)/6.785(1)/6.562(1) Å, β=106.53(3)/106.20(3)/106.50(3)°, V=718.8(2)/693.0(2)/638.3(2) Å3, R(F)=0.0225/0.0204/0.0270, respectively. The topology of the novel structure type contains isolated horseshoe-shaped Si3O10 groups (Si–Si–Si=93.15–95.98°), Si2O7 groups (Si–Obridge–Si=180°, symmetry-restricted) and edge-sharing M(1)O6 and M(2)O6 octahedra. Single-crystal Raman spectra of the title compounds were measured and compared with Raman spectroscopic data of chemically and topologically related disilicates and trisilicates, including BaY2(Si3O10) and SrY2(Si3O10). The band assignments are supported by additional theoretical calculation of Raman vibrations by DFT methods.
View of BaY4(Si2O7)(Si3O10) along [100], showing zigzag chains and the tri- and disilicate groups. The unit cell is outlined.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 207, November 2013, Pages 94–104