Structural, morphological and spectroscopic properties of Eu3+-doped rare earth fluorides synthesized by the hydrothermalmethod

Rare earth fluorides (REF3, RE=Y, La, Gd or Yb) doped with 5% of Eu3+ ions were synthesized via the hydrothermal method and their physicochemical properties were compared. The synthesis was carried out in an aqueous medium at elevated pressure and temperature. The reaction was performed in situ, with use of NaBF4 as a source of fluoride ions. Structural and morphological properties of obtained nanophosphors were characterized with the use of powder X-ray diffraction (XRD), transmission electron microscopy (TEM) and Raman spectroscopy. Synthesized products were nanocrystalline with hexagonal or orthorhombic crystal structures. They showed different morphology, from nanoplates to nanorings, depending on the used REF3 fluoride as the host for the Eu3+ ions. The elemental composition was confirmed by the energy-dispersive X-ray spectroscopy (EDX) results. Spectroscopic properties were investigated by measuring the excitation and emission spectra. Also luminescence lifetimes were determined. The synthesized materials showed bright red luminescence, due to the presence of Eu3+ ions in their structure.

Luminescence spectra of the REF3:Eu3+ (RE=Y, La, Gd and Yb) fluorides and their TEM images as background.Figure optionsDownload as PowerPoint slideHighlights
► Nanocrystalline fluorides were synthesized using modified hydrothermal method.
► Structural and morphological properties of in situ prepared nanomaterials were studied.
► Luminescence properties of REF3:Eu3+ (RE=Y, La, Gd, Yb) were compared and investigated.