کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1331520 979007 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ionothermal synthesis of the mixed-anion material, Ba3Cl4CO3
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Ionothermal synthesis of the mixed-anion material, Ba3Cl4CO3
چکیده انگلیسی

A low-temperature ionothermal method for the facile synthesis of the halide carbonate, Ba3Cl4CO3, in single-crystalline form has been developed. This has enabled the first determination of the crystal structure of this material to be carried out. Analysis of single-crystal X-ray diffraction data indicates that barium chloride carbonate crystallises in the orthorhombic space group Pnma (Z=4), with a=8.4074(11), b=9.5886(12), c=12.4833(15) Å (Rw=0.0392). It exhibits a complex structure in which a three-dimensional network is formed from cross-linking of chains of anion-centred octahedra that share faces.

Graphical AbstractIonothermal synthesis has provided single crystals of the mixed-anion material barium chloride carbonate, enabling the first determination of the complex crystal structure of this phase to be performed.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Solid State Chemistry - Volume 182, Issue 9, September 2009, Pages 2333–2337
نویسندگان
, , ,