کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1331520 | 979007 | 2009 | 5 صفحه PDF | دانلود رایگان |

A low-temperature ionothermal method for the facile synthesis of the halide carbonate, Ba3Cl4CO3, in single-crystalline form has been developed. This has enabled the first determination of the crystal structure of this material to be carried out. Analysis of single-crystal X-ray diffraction data indicates that barium chloride carbonate crystallises in the orthorhombic space group Pnma (Z=4), with a=8.4074(11), b=9.5886(12), c=12.4833(15) Å (Rw=0.0392). It exhibits a complex structure in which a three-dimensional network is formed from cross-linking of chains of anion-centred octahedra that share faces.
Graphical AbstractIonothermal synthesis has provided single crystals of the mixed-anion material barium chloride carbonate, enabling the first determination of the complex crystal structure of this phase to be performed.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 182, Issue 9, September 2009, Pages 2333–2337