کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1331697 | 979012 | 2009 | 5 صفحه PDF | دانلود رایگان |
Ferroelastic β′-Gd2(MoO4)3, (GMO), crystals are formed through the crystallization of 21.25Gd2O3–63.75MoO3–15B2O3 glass (mol%), and two scientific curious phenomena are observed. (1) GMO crystals formed in the crystallization break into small pieces with a triangular prism or pyramid shape having a length of 50–500 μm spontaneously during the crystallizations in the inside of an electric furnace, not during the cooling in air after the crystallization. This phenomenon is called “self-powdering phenomenon during crystallization” in this paper. (2) Each self-powdered GMO crystal grain shows a periodic domain structure with different refractive indices, and a spatially periodic second harmonic generation (SHG) depending on the domain structure is observed. It is proposed from polarized micro-Raman scattering spectra and the azimuthal dependence of second harmonic intensities that GMO crystals are oriented in each crystal grain and the orientation of (MoO4)2− tetrahedra in GMO crystals changes periodically due to spontaneous strains in ferroelastic GMO crystals.
This figure shows the polarized optical photograph at room temperature for a particle (piece) obtained by a heat treatment of the glass at 590 °C for 2 h in an electric furnace in air. This particle was obtained through the self-powdering behavior in the crystallization of glass. The periodic domain structure is observed. Ferroelastic β′-Gd2(MoO4)3 crystals are formed in the particle, and second harmonic generations are detected, depending on the domain structure.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 182, Issue 8, August 2009, Pages 2269–2273