کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1332176 | 979032 | 2008 | 7 صفحه PDF | دانلود رایگان |
This article describes the preparation of mesoporous rod-like F–N-codoped TiO2 powder photocatalysts with anatase phase via a sol–gel route at the temperature of 373 K, using cetyltrimethyl ammonium bromide (CTAB) as surfactant. The as-prepared photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and UV–visible diffuse reflectance spectra (UV–vis DRS). The results showed that the photocatalysts possessed a homogeneous pore diameter and a high surface area of 106.3–160.7 m3 g−1. The increasing CTAB reactive concentration extended the visible-light absorption up to 600 nm. The F–N-codoped TiO2 powders exhibited significant higher adsorption capacity for methyl orange (MO) than that of Degussa P25 and showed more than 6 times higher visible-light-induced catalytic degradation for MO than that of P25.
The introduction of surfactant CTAB not only extended the visible light absorption of mesoporous F–N-codoped TiO2 up to 600 nm but also significantly enhanced the adsorption capacity and visible-light-induced degradation for methyl orange.Mesoporous rod-like F–N-codoped TiO2 powder photocatalysts were synthesized via a sol–gel route at low temperature of 373 K.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 181, Issue 8, August 2008, Pages 1936–1942