Direct synthesis of porous NiO nanowall arrays on conductive substrates for supercapacitor application

Porous NiO nanowall arrays (NWAs) grown on flexible Fe–Co–Ni alloy have been successfully synthesized by using nullaginite (Ni2(OH)2CO3) as precursor and investigated as supercapacitor electrodes. In details, we adopted a simple hydrothermal method to realize Ni2(OH)2CO3 NWAs and examined their robust mechanical adhesion to substrate via a long-time ultrasonication test. Porous NiO NWAs were then obtained by a post-calcination towards precursors at 500 °C in nitrogen atmosphere. Electrochemical properties of as-synthesized NiO NWAs were evaluated by cyclic voltammetry and galvanostatic charge/discharge; porous NiO NWAs electrode delivered a specific capacitance of 270 F/g (0.67 A/g); even at high current densities, the electrode could still deliver a high capacitance up to 236 F/g (13.35 A/g). Meanwhile, it exhibited excellent cycle lifetime with ∼93% specific capacitance kept after 4000 cycles. These results suggest that as-made porous NiO NWAs electrode is a promising candidate for future thin-film supercapacitors and other microelectronic systems.

Porous NiO nanowall arrays (NWAs) grown on alloy substrate have been made using nullaginite as precursor and studied as supercapacitor electrodes. Porous nanowalls interconnected with each other resulting in the formation of extended-network architectures and exhibited excellent capacitor properties. NiO NWAs electrode delivered a capacitance of 270 F/g (0.67 A/g); even at high current density, the electrode could still deliver a high capacitance up to 236 F/g (13.35 A/g). Besides, it exhibited excellent cycle lifetime with ∼93% capacitance kept after 4000 cycles. These remarkable results made it possible for mass production of NiO NWAs and future thin-film microelectronic applications.Figure optionsDownload as PowerPoint slideResearch highlights
► Large-scale nullaginite (Ni2(OH)2CO3) nanowall arrays (NWAs) have been synthesized on flexible alloy substrate by a facile hydrothermal method.
► Ultrasonication test has been conducted to demonstrate the robust mechanical adhesion between NWAs and substrate.
► As supercapacitor electrodes porous NiO NWAs obtained by a post-calcination towards Ni2(OH)2CO3 precursors have exhibited excellent electrochemical properties.