کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1333411 979077 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Template free fabrication of hollow hematite spheres via a one-pot polyoxometalate-assisted hydrolysis process
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Template free fabrication of hollow hematite spheres via a one-pot polyoxometalate-assisted hydrolysis process
چکیده انگلیسی

Uniform hollow hematite (α-Fe2O3) spheres with diameter of about 600–700 nm and shell thickness lower than 100 nm are obtained by direct hydrothermal treatment of dilute FeCl3 and tungstophosphoric acid H3PW12O40 solution at 180 °C. The hollow spheres are composed of robust shells with small nanoparticles standing out of the surface and present a high-surface area and a weak ferromagnetic behavior at room temperature. The effect of concentration of H3PW12O40, reaction time and temperature for the formation of the hollow spheres are investigated in series of experiments. The formation of the hollow spheres may be ascribed to a polyoxometalte-assisted forced hydrolysis and dissolution process.

Uniform hollow hematite (α-Fe2O3) spheres with diameter of about 600–700 nm and shell thickness lower than 100 nm are obtained by direct hydrothermal treatment of dilute FeCl3 and tungstophosphoric acid H3PW12O40 solution at 180 °C. The hollow spheres present a high surface area and weak ferromagnetic behavior at room temperature.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Solid State Chemistry - Volume 180, Issue 2, February 2007, Pages 489–495
نویسندگان
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