Synthesis, crystal growth and structure of Mg containing β-rhombohedral boron: MgB17.4

For the first time, single crystals of Mg containing β-rhombohedral boron MgB17.4 were synthesised from the elements in a Mg/Cu melt at 1600 °C. The crystal structure determined by the refinement of single crystal data (space group R-3m  , a=10.991(2)Å, c=24.161(4)Å, 890 reflections, 123 variables, R1(F)=0.049R1(F)=0.049, wR2(I)=0.122wR2(I)=0.122) improves and modifies the former structure model derived from earlier investigations on powder samples. Mg is located on four different positions with partial occupation. While the occupation of the sites D (53.3%), E (91%) and F (7.2%) is already known from other boron-rich borides related to β-rhombohedral boron, the occupation of the fourth position (18h, 6.7%) is observed for the first time. Two boron positions show partial occupation. The summation reveals the composition MgB17.4 and Mg5.85B101.9, respectively, confirmed by WDX measurements. The single crystals of MgB17.4 show the highest Mg content ever found. Preliminary measurements indicate no superconductivity.

Unit cell of MgB17.4 (rhombohedral setting).Figure optionsDownload as PowerPoint slide