کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1334026 979131 2005 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Syntheses and characterization of the samarium(III)–copper(II) 3D coordination network constructed by iminodiacetic acid
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Syntheses and characterization of the samarium(III)–copper(II) 3D coordination network constructed by iminodiacetic acid
چکیده انگلیسی

The hydrothermal reaction of Sm2O3 with iminodiacetic acid (H2Idad), CuO, and H2O with a mole ratio of 1:2:4:300 resulted in the formation of one nanoporous 3D open framework Cu(II)–Sm(III) coordination polymer, [{Sm2Cu3(Idad)6}·8H2O]n. Investigation shows that the coordination polymer possesses high thermal and structural stability. Temperature-dependent magnetic susceptibilities of the coordination polymer with the similar structure, [{Gd2Cu3(Idad)6}·8H2O]n, were studied.

A reaction between Sm2O3, iminodiacetic acid (H2Idad), CuO, and H2O has allowed the synthesis of one nanoporous 3D open framework Cu(II)–Sm(III) coordination polymer, [{Sm2Cu3(Idad)6}·8H2O]n (1) and then magnetic behavior of the compound, [{Gd2Cu3(Idad)6}·8H2O]n (2), with a similar structure was studied.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Solid State Chemistry - Volume 178, Issue 12, December 2005, Pages 3729–3734
نویسندگان
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